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汤 征, 李长真, 尹 镝, 朱本鹏, 汪丽莉, 王俊峰, 熊 鋭, 王取泉, 石 兢

Single crystal growth and magnetic properties of strong geometric frustrated magnetic pyrochlore Dy2Ti2O7

Tang Zheng, Li Chang-Zhen, Yin Di, Zhu Ben-Peng, Wang Li-Li, Wang Jun-Feng, Xiong Rui, Wang Qu-Quan, Shi Jing
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  • 利用红外光源浮区法生长出大尺寸、高质量的磁失措自旋冰化合物Dy2Ti2O7单晶体.X射线衍射实验证实晶体具有面心立方结构,空间群为Fd3m,晶胞参数a=1.0112(2) nm,[111]和[400]方向X射线衍射摇摆曲线半高宽分别仅为0.07°和0.05°.直流磁化率与温度关系测量给出晶体的Van Vleck顺磁因子为2.46×10-5 m3/mol,有效磁矩μeff=10.24(4)μB,Cure-Weiss温度ΘCW=1.1 K,揭示Dy2Ti2O7具有弱的铁磁性.对磁性起源的综合分析表明,该自旋冰晶体磁性质主要来源于磁偶极相互作用,且相关最近邻长程偶极相互作用能量标度Dnn=3.00 K.
    Large, high quality single crystals of Dy2Ti2O7 have been successfully grown by the floating zone technique in an infrared image furnace. The obtained single crystal has been characterized by X-ray diffraction at room temperature and is shown to have the face centred cubic structure, Fd3m, with a room temperature lattice parameter a=1.0112(2) nm. The full-width at half-maximum of rocking curves of [111] and [400] Bragg peaks are 0.07° and 0.05°, respectively. Magnetic susceptibility measurements give a Van Vleck paramagnetic parameter of 2.46×10-5m3/mol, the effective moment μeff=10.24(4)μB and Cure-Weiss temperature ΘCW=1.1 K, indicating weak ferromagnetism for the Dy2Ti2O7 single crystal. The comparative studies of the experiment and theoretical analysis reveal that the long-ranged dipole-dipole interactions dominate the magnetic behaviors of this kind of spin ice system, and the dipolar energy scale Dnn=3.00 K.
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    出版历程
    • 收稿日期:2005-12-06
    • 修回日期:2006-07-20
    • 刊出日期:2006-06-05

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