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研究了经历不同时间退火后, Fe 80Si 9B 10Cu 1非晶合金结构弛豫过程中纳米尺度结构不均匀性的演变及其对合金磁性能的影响. 基于小角X射线散射和原子力显微镜分析, 随着弛豫的进行, 合金的纳米尺度结构不均匀性逐渐衰减. 结合穆斯堡尔谱分析结果, 弛豫态合金综合软磁性能的提高可归因于纳米尺度结构不均匀性的减弱. 从流变单元模型来看, 随着弛豫程度的加深, 流变单元的体积分数显著降低, 部分流变单元湮灭并转化为理想弹性基体. 一方面, 弛豫态样品的原子结构排列更加紧密, 磁交换相互作用更强, 饱和磁感应强度也更高; 另一方面, 准位错偶极子的数量密度随着流变单元在弛豫过程中的湮灭而逐渐减小, 磁畴壁的钉扎效应减弱, 合金的磁各向异性下降, 矫顽力降低. 本文从结构不均匀性的角度研究了Fe 80Si 9B 10Cu 1非晶合金弛豫过程中磁性能变化的结构机制, 有助于建立铁基非晶合金结构和磁性能之间的关联性.The evolution of nanoscale structural heterogeneity and its effect on magnetic properties of Fe 80Si 9B 10Cu 1amorphous alloy during structural relaxation after being annealed for different times are investigated in this work. The nanoscale structural heterogeneity is found to degenerate gradually with relaxation by using the small-angle X-ray scattering and atomic force microscope. Combined with Mössbauer spectroscopy analysis results, the enhanced comprehensive soft magnetic properties of the relaxed alloys can be attributed to the degeneration of nanoscale structural heterogeneity. From the flow unit model, the volume fraction of flow units decreases with relaxation proceeding, and some of the flow units annihilate and transform into the ideal elastic matrix. On the one hand, the relaxed sample with greater packing density has stronger magnetic exchange interaction and higher saturation magnetic flux intensity. On the other hand, the number density of quasi-dislocation dipoles decreases with the annihilation of flow units in the relaxation process, leading the pinning effect of the domain wall to be weakened. Consequently, the magnetic anisotropy decreases after relaxation, which results in the reduction of coercivity. In this work, the structural mechanism of the evolution of magnetic properties in the relaxation process of Fe 80Si 9B 10Cu 1amorphous alloy is investigated from the perspective of structural heterogeneity, which is helpful in establishing the correlation between the structure and magnetic properties of Fe-based amorphous alloys.
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Samples Bhfa/T IS/
(mm·s–1)DTI/
(mm·s–1)QS/
(mm·s–1)As-quenched 24.87 –0.054 0.0062 –0.014 3 min 25.46 –0.075 0.0053 –0.023 5 min 25.63 –0.066 0.0066 –0.018 8 min 25.85 –0.096 0.0076 –0.019 
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