CeRh2As2, as a recently discovered Ce-based 122-type heavy-fermion superconductor, has attracted much attention due to its non-Fermi-liquid behavior and two-phase superconductivity. The tetragonal crystal structure of CeRh2As2 maintains global centrosymmetry, which makes even-parity and odd-parity superconducting states different rather than mixed. The Ce site exhibits local inversion symmetry breaking, which results in staggered Rashba spin-orbit coupling. This may lead to the c axis field-induced transition between two superconducting phases and high critical field. Given the novel physics in CeRh2As2, including a possible quantum critical point and a spin-fluctuation-mediated superconducting pairing mechanism, the ultra-low-temperature electrical and thermal transport properties of CeRh2As2 under various magnetic fields are investigated in this work. The zero-field resistivity reveals a superconducting transition at the critical temperature Tc = 0.34 K. At a magnetic field of 1 T, a minimum resistivity appears near T0$ \approx $0.42 K, which may be due to partial gap opening caused by Fermi surface nesting, indicating that the system enters into a magnetically ordered state, which is not observed in zero field. In the temperature range from T0 to 2 K, the system exhibits non-Fermi-liquid behavior $ \rho\sim{{T}}^{0.44} $, indicating proximity to a quantum critical point. The superconducting transition is fully suppressed at 7 T, with resistivity recovering Fermi-liquid behavior at low temperature. No significant anomaly is observed in the zero-field thermal conductivity of CeRh2As2 near Tc. This absence of anomaly may be attributed to the high residual resistivity of the sample, and the reduction in carrier density during the superconducting transition and the T0 phase transition. It requires optimizing single crystal growth to reduce the effects of lattice defects or chemical disorder on thermal transport. Upon applying magnetic field, the thermal conductivity curve exhibits a small upward shift relative to its zero-field curve. At 0.15 K, thermal conductivity rises with the increase of magnetic field and is saturated at higher fields (above 5 T). In the normal state at 7 T, it is found that the electrical resistivity and thermal conductivity satisfy the Wiedemann-Franz law, indicating that the charge transfer and the heat transport are governed by the same quasiparticles, which is consistent with the Fermi-liquid behavior observed in resistivity under this field.